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2 edition of aqueous chlorination of organic compounds found in the catalog.

aqueous chlorination of organic compounds

R. C. Pierce

aqueous chlorination of organic compounds

chemical reactivity and effects on environmental quality

by R. C. Pierce

  • 99 Want to read
  • 30 Currently reading

Published by National Research Council of Canada, NRC Associate Committee on Scientific Criteria for Environmental Quality in Ottawa, Canada .
Written in English


Edition Notes

Includes bibliographical references.

Statementby Ronald C. Pierce.
SeriesNRCC -- no. 16450
Classifications
LC ClassificationsMLCM 2008/43686 (Q)
The Physical Object
Pagination136 p. :
Number of Pages136
ID Numbers
Open LibraryOL22667536M
LC Control Number2008396788

5 Effect of Cl 2 on zRecent study on effect of chlorine on E. coli zTested 6 strains of OH7 at 4 Cl 2 levels mg/L mg/L mg/L mg/L X 0 1 and 2 mins contact time z5/6 isolates + E. coli control strain were highly susceptible to chlorine z>7 log10 reduction of each of these strains by mg/L free chlorine within 1 min (CT value = )File Size: KB. Chlorination of aqueous solutions containing organic nitrogen: Analysis and detection with MIMS. Chii Shang, Purdue University. Abstract. In most “real-world” applications of chlorine to aqueous systems, the interactions between chlorine and organic N-compounds are of concern in terms of both disinfection efficacy and analytical by: 1.

Abstract. This paper describes the formation of organic chlorine compounds like chloroform, and chlorinated acetic acids, acetones, pyruvic acids, maleic and fumaric acids, acetonitriles and acetamides in the chloroperoxidase-mediated reaction between chloride and humic material Chemical chlorination may also occur to a small extent, because hydrogen peroxide may give rise to active by: The chemistry of hypochlorite ion in aqueous solutions is discussed in the monograph on chlorinated drinking-water (p. 50). All hypochlorite salts, as well as chlorine itself, in aqueous solution produce equilibrium mixtures of hypochlorous acid, hypochlorite ion and chlorine. In concentrated solutions, hypochlorite ion tends to disproportionate to form chlorate and chloride ions.

The aqueous chemistry of chlorine is significantly pH dependent, thus various species of this oxidant with different reactivities with micropollutants, may be present in solutions [34 Missing: book. Chlorinated Solvent Chemistry: Structures, Nomenclature and Properties; Introduction. Chlorinated solvents are a large family of organic solvents that contain chlorine atoms in their molecular structure. They were first produced in Germany in the s, and widespread use in the United States (U.S.) began after World War II.


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Aqueous chlorination of organic compounds by R. C. Pierce Download PDF EPUB FB2

The aqueous chlorination of organic compounds: Chemical reactivity and effects on environmental quality (Publication ; no. NRCC ) Unknown Binding – January 1, by R.

C Pierce (Author)Author: R. C Pierce. Summary This chapter contains sections titled: Dissolution and Hydrolysis of Chlorine Dissociation of Hypochlorous Acid Chlorine Speciation in Concentrated Solutions Hypochlorite Solutions Oxidatio. The initial chlorination kinetics of several substituted dihydroxybenzenes, including chlorinated resorcinol compounds, was studied over the pH range of 2−12 at 22 °C.

For each of the resorcinol substrates, the apparent chlorination rates are a minimum in the pH range of 3−6 and a maximum at pH values between 8− A mechanism that involves the reaction of HOCl with ArX(OH)2, ArX(OH)O Cited by: To assess the estrogenic activity potentially stemming from bisphenol A (BPA) in drinking water, APCI/LC/MS and NMR were used to identify the products of its aqueous chlorination under the following conditions: μg/L bisphenol A and mg/L sodium hypochlorite (pH ) at 25 °C.

The 13 products (4-chloro-BPA; 2,6‘-dichloro-BPA; 2,6-dichloro-BPA; 2,2‘,6‘-trichloro-BPA; 2,2‘,6,6 Cited by: Thirty organic compounds were selected to investigate their chloroform formation characteristics during chlorination with sodium hypochlorite at pH-values and These experiments were conducted under conditions similar to those applied on the chlorination of raw by:   The aqueous chlorination kinetics of six endocrine disruptors (EDs: 4-n-nonylphenol, β-estradiol, estrone, estriol, 17α-ethinylestradiol, progesterone) were studied in the − pH range, at 20 ± 2 °C, in the presence of an excess of total chlorine.

Under aqueous chlorination of organic compounds book conditions, all molecules with a phenolic group in their structure were rapidly oxidized by chlorine, whereas progesterone Cited by: Aqueous Chlorination Kinetics and Mechanism of Substituted Dihydroxybenzenes. Environmental Science & Technology30 (7), DOI: /est.

Annika. Smeds, Robert. Franzen, and Leif. Kronberg. Occurrence of Some Chlorinated Enol Lactones and Cyclopentene-1,3-Diones in Chlorine-Treated by: The Journal of Organic Chemistry66 (17), DOI: /jou. Chii Shang, Woei-Long Gong, and, Ernest R.

Blatchley III. Breakpoint Chemistry and Volatile Byproduct Formation Resulting from Chlorination of Model Organic-N by: This report is a review of the reactions of aqueous chlorine and chlorine dioxide with organic compounds *Food Science and Human Nutrition Department, University of Florida, Gainesville, FL tAuthorto whomcorrespondence andrequestsforreprints should beaddressed.

Table 1. Useofchlorine in thefoodindustry.a Use Concentration, ppm. In effect, the aqueous chemistry of chlorine is greatly pH-dependent, and various species of this oxidant may be present in solution, leading to significant Cited by: Chlorination is a vital reaction of organic chemistry because of extensive variety of uses of chloro-substituted organic compounds in fine chemicals and pharmaceutical intermediates.

Consequently, large number of methods are accessible in the prior art for chlorination of organic compounds File Size: 1MB.

Cite this article. Rapson, W.H., Nazar, M.A. & Butsky, V.V. Mutagenicity produced by aqueous chlorination of organic compounds. by: Chlorination is an important reaction of organic chemistry because of wide variety of uses of chloro-substituted organic compounds in fine chemicals and pharmaceutical intermediates.

Therefore, large number of methods are available in the prior art for chlorination of organic compounds Missing: book. The aqueous chlorination of organic compounds: chemical reactivity and effects on environmental quality.

Abstract. While both aqueous bromine (HOBr/OBr −) and chlorine (HOCl/OCl −) react with natural organic matter (NOM) during water treatment, limited direct parallel comparison of bromine versus chlorine has been conducted.

Experiments with model compounds and natural waters indicated more efficient substitution reactions with bromine than chlorine. Kinetic experiments with NOM isolates with Cited by: In the case of organic compounds, second-order rate constants for chlorination vary over 10 orders of magnitude (i.e.

organic compounds are possible pathways. However, from a kinetic point of view, usually only electrophilic attack is by: Unfortunately, little is known about the nature of the reactions of chlorine with organic food constituents. This presentation reviews published information concerning the reactions of chlorine gas (Cl2[g]), aqueous chlorine, and ClO2 with model food compounds, the fate of chlorine during the chlorination of specific food products, and the potential toxicity of the reaction by: The reactions of phenolic substances with hypochlorite in water were investigated by means of gas chromatography-mass spectrometry.

Chlorinated and me Cited by: Similarly to H 2 O 2 oxidation, Westerhoff et al. () found that aromatic compounds of natural organic matter are more reactive with aqueous chlorine than aliphatic compounds, which might Missing: book. Title:Aqueous chemistry of chlorine: chemistry, analysis, and environmental fate of reactive oxidant species.

Aqueous chemistry of chlorine: chemistry, analysis, and environmental fate of. Many researches have been done on characteristics of removing single amine-containing pharmaceutical compounds by aqueous chlorination (Pinkston and Sedlak,Dodd and Huang,Bedner and.

Chlorine added to drinking water as a disinfectant is a concern of this generation. This is because chlorine reacts with dissolved organic compounds to form polychlorinated complexes that are carcinogenic. Available methods for the removal of chlorine and chlorinated compounds include adsorption, precipitation, electrolysis and ozonation, but some result in the generation of more toxic by: 5.4-chlororesorcinol 5-chlorouracil acetone ammonia amperometric amperometric titration aquatic aqueous chlorine aromatic bioaccumulation bioassay blowdown bromine Brungs cancer carbon carcinogenic Chem chemical chemistry chlo chloramines chlorinated organics chlorine concentrations chlorine demand chlorine dose chlorine levels chlorine residual.